In the evolving landscape of global education, Psychosocial Mentoring in the Framework of Education 5.0 serves as a transformative guide for educators, mentors, and institutions committed to holistic learner development. Rooted in the values of human dignity, empathy, and sustainability, this book bridges advanced technological integration with the nurturing of emotional intelligence, critical thinking, and social responsibility. Through a comprehensive exploration of facilitation techniques, mentoring frameworks, and strategic interventions, it equips educators to evolve from content deliverers to compassionate mentors. Drawing on insights from Education 5.0, the authors present actionable methods-like role plays, success stories, and design thinking-to foster psychosocial competencies among learners. This book is not just a manual but a vision, encouraging a shift from robotic education to value-driven, human-centric learning ecosystems.